Palladium (II) and platinum (II) aqueous solutions.: Evidence for the solvation of the [PdCl4]2- and [PtCl4]2- ions

被引：43

作者：

Caminiti, R

Carbone, M

Sadun, C

机构：

[1] Univ Rome La Sapienza, Ist Nazl Fis Mat, Dept Chem, I-00185 Rome, Italy

[2] Univ Roma Tor Vergata, Dept Chem Sci & Technol, I-00133 Rome, Italy

来源：

JOURNAL OF MOLECULAR LIQUIDS | 1998年 / 75卷 / 02期

关键词：

D O I：

10.1016/S0167-7322(98)82003-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The isomorphic substitution applied to solutions of NH4PtCl4 and NH4PdCl4 allows to show the existence of 2 bound water molecules at the apical sites of PtCl42- and PdCl42- ions. The Pt(Pd)-H2O distance results equal to 2.77 Angstrom. (C) 1998 Elsevier Science B.V.

引用

页码：149 / 158

页数：10

共 38 条

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