Polymer (PVP) supported ferric chloride: an efficient and recyclable heterogeneous catalyst for high yield synthesis of 1,5-benzodiazepine derivatives under solvent free conditions and microwave irradiation

被引:83
作者
Chari, MA [1 ]
Syamasundar, K [1 ]
机构
[1] JNT Univ, Coll Engn, Dept Chem, Hyderabad 500072, Andhra Pradesh, India
关键词
o-phenylenediamines; ketones; polymer (PVP) supported ferric chloride; benzodiazepines;
D O I
10.1016/j.catcom.2004.10.009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Polymer (PVP) supported ferric chloride catalyzes efficiently the condensation of o-phenylenediamines with ketones under solvent free conditions to afford the corresponding 1,5-benzodiazepine derivatives in high yields. The reaction proceeds efficiently under ambient conditions giving excellent yields (85-96%). (C) 2004 Published by Elsevier B.V.
引用
收藏
页码:67 / 70
页数:4
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