Nanocrystalline CdS-water-soluble conjugated-polymers: High performance photoelectrochemical cells

被引:40
作者
Lee, Wonjoo
Mane, Rajaram S.
Min, Sun-Ki
Yoon, Tae Hyun
Han, Sung-Hwan
Lee, Soo-Hyoung
机构
[1] Hanyang Univ, Dept Chem, Inorgan Nanomat Lab, Seoul 133791, South Korea
[2] Chonbuk Natl Univ, Div Environm & Chem Engn, Jeonju 561756, South Korea
关键词
D O I
10.1063/1.2752021
中图分类号
O59 [应用物理学];
学科分类号
摘要
Enhanced photoelectrochemical cell performance of nanocrystalline CdS-water-soluble conjugated-polymer sensitizers was demonstrated. The water-soluble polymers with quaternary pyridinium salts can be easily layered after dipping nanocrystalline CdS films in the aqueous polymer solution. The 2.37% energy conversion efficiency of CdS-poly(2-ethynyl-N-carboxypropylpyridiniumbromide) (LM 3) conjugated-polymer sensitizer was significantly higher than that of the bare (0.57%) and CdS-poly(2-ethynyl-N-aminopropylpyridiniumbromide) (LM 2) conjugated-polymer sensitizer (2.15%) under AM1.5 condition (80 mW/cm(2)). (c) 2007 American Institute of Physics.
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页数:3
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