Electric dipole polarizability of As4, a challenging problem for both experiment and theory

被引：22

作者：

Hohm, U

Goebel, D

Karamanis, P

Maroulis, G

机构：

[1] Tech Univ Carolo Wilhelmina Braunschweig, Inst Theoret & Phys Chem, D-38106 Braunschweig, Germany

[2] Univ Patras, Dept Chem, GR-26500 Patras, Greece

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 1998年 / 102卷 / 08期

关键词：

D O I：

10.1021/jp973469y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An experimental value of 116.7 +/- 1.1 e(2)a(0)(2)E(h)(-1) for the Static dipole polarizability of As-4 is deduced from the analysis of refractivity measurements in arsenic vapor. This is in close agreement with the theoretical result of 119.5 +/- 3.6 e(2)a(0)(2)E(h)(-1), obtained from ab initio finite-field many-body perturbation theory and coupled-cluster calculations.

引用

页码：1237 / 1240

页数：4

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