Use of heterogenized dialdimine ligands in asymmetric transfer hydrogenation

被引：53

作者：

Breysse, E ^{[1
]}

Pinel, C ^{[1
]}

Lemaire, M ^{[1
]}

机构：

[1] UCBL, CPE, Inst Rech Catalyse, Lab Catalyse & Synth Organ, F-69622 Villeurbanne, France

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 06期

关键词：

D O I：

10.1016/S0957-4166(98)00067-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Heterogenized dialdimine ligands complexed to iridium were tested in the asymmetric transfer hydrogenation of acetophenone. E.e.s of up to 70% were achieved but the recycling was unsatisfactory. When such ligands were used in asymmetric epoxidation of styrene, a modest e.e. of 15% was achieved. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：897 / 900

页数：4

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