Efficiency of a solid polymer fuel cell operating on ethanol

被引:24
作者
Ioannides, T [1 ]
Neophytides, S [1 ]
机构
[1] Inst Chem Engn & High Temp Chem Proc, ICE HT, Fdn Res & Technol Hellas, FORTH, GR-26500 Patras, Greece
关键词
ethanol; solid polymer fuel cell; reforming; partial oxidation; thermodynamic analysis;
D O I
10.1016/S0378-7753(00)00473-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The efficiency of a solid polymer fuel cell (SPFC) system operating on ethanol fuel has been analyzed as a function of operating parameters focusing on vehicle and stationary applications. Two types of ethanol processors - employing either steam reforming or partial oxidation (POX) steps - have been considered and their performance has been investigated by thermodynamic analysis. SPFC operation has been analyzed by an available parametric model. It has been found that dilute ethanol-water mixtures (similar to 55% v/v EtOH) are the most suitable for stationary applications with a steam reformer (SR)-SPFC system. Regarding vehicle applications, pure ethanol (similar to 95% v/v EtOH) appears to be the best fuel with a POX-SPFC system. Efficiencies in the case of an ideal ethanol processor can be of the order of 60% under low load conditions and 30-35% at peak power, while efficiencies with an actual processor are 80-85% of the above values. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:150 / 156
页数:7
相关论文
共 14 条
  • [1] Electrocatalysts for fuel cells
    Acres, GJK
    Frost, JC
    Hards, GA
    Potter, RJ
    Ralph, TR
    Thompsett, D
    Burstein, GT
    Hutchings, GJ
    [J]. CATALYSIS TODAY, 1997, 38 (04) : 393 - 400
  • [2] PERFORMANCE MODELING OF THE BALLARD-MARK-IV SOLD POLYMER ELECTROLYTE FUEL-CELL .2. EMPIRICAL-MODEL DEVELOPMENT
    AMPHLETT, JC
    BAUMERT, RM
    MANN, RF
    PEPPLEY, BA
    ROBERGE, PR
    HARRIS, TJ
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (01) : 9 - 15
  • [3] AMPHLETT JC, 1995, J ELECTROCHEM SOC, V142, P1, DOI 10.1149/1.2043866
  • [4] FUEL-CELLS AND HYDROGEN FUEL
    APPLEBY, AJ
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1994, 19 (02) : 175 - 180
  • [5] Dean JA., 1992, Lange's handbook of chemistry
  • [6] FULLER TF, 1997, ELECTROCHEMICAL FAL, P26
  • [7] Removal of carbon monoxide from hydrogen-rich fuels by selective oxidation over platinum catalyst supported on zeolite
    Igarashi, H
    Uchida, H
    Suzuki, M
    Sasaki, Y
    Watanabe, M
    [J]. APPLIED CATALYSIS A-GENERAL, 1997, 159 (1-2) : 159 - 169
  • [8] IONNIDES T, IN PRESS J POWER SOU
  • [9] Kinetics of the selective low-temperature oxidation of CO in H2-rich gas over Au/α-Fe2O(3
    Kahlich, MJ
    Gasteiger, HA
    Behm, RJ
    [J]. JOURNAL OF CATALYSIS, 1999, 182 (02) : 430 - 440
  • [10] Compact hydrogen production systems for solid polymer fuel cells
    Ledjeff-Hey, K
    Formanski, V
    Kalk, T
    Roes, J
    [J]. JOURNAL OF POWER SOURCES, 1998, 71 (1-2) : 199 - 207