Enantioselective aggregation of cobalt(III) octahedrons in a one-dimensional S-bridged CoIIIAgI array that leads to spontaneous resolution

被引：13

作者：

Konno, T ^{[1
]}

Tokuda, K

Okamoto, K

Hirotsu, M

机构：

[1] Gunma Univ, Fac Engn, Dept Chem, Gunma 3768515, Japan

[2] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 11期

关键词：

D O I：

10.1246/cl.2000.1258

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of [Co(aet)(en)(2)](NO3)(2) (1(NO3)(2); aet = 2-aminoethanethiolate; en = ethylenediamine) with AgNO3 in water produced a novel S-bridged (CoAgI)-Ag-III chain complex-polymer, [Ag(Co(aet)(en)(2)}](NO3)(3) (3(NO3)(3)), by way of a (CoAgCoIII)-Ag-III-Co-I trinuclear complex, [AgICo(aet)(en)(2)}(2)](NO3)(5) (2(NO3)(5)) The crystal structure of 3(NO3)(3), which crystallizes as a conglomerate, was determined by X-ray crystallography.

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页码：1258 / 1259

页数：2

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