A model synthesis of the bicyclic core structure of the furanoheliangolide sesquiterpenes

被引：11

作者：

Constantino, MG ^{[1
]}

Beatriz, A ^{[1
]}

da Silva, GVJ ^{[1
]}

机构：

[1] Univ Sao Paulo, Dept Quim, Fac Filosofia Ciencias & Letras Ribeirao Pret, BR-14040901 Ribeirao Preto, Brazil

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 36期

关键词：

D O I：

10.1016/S0040-4039(00)01198-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A bicyclo[6.2.1]undecane structure, a model for the core structure of several biologically active furanoheliangolide sesquiterpenes, was synthesized through a retro-aldol reaction from a tricyclo-[6.2.1.0(2,7)]undecane. The required tricyclic compound was prepared by a Diels-Alder reaction followed by minor transformations. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：7001 / 7004

页数：4

共 5 条

[1]

ALBRECHT W, 1906, LIEBIGS ANN CHEM, V31, P384

[2]

MARCHAND AP, 1991, SYNTHESIS-STUTTGART, P198

[3] IMPROVED SYNTHESIS OF RACEMIC AND OPTICALLY-ACTIVE 4-HYDROXYCYCLOHEX-2-EN-1-ONE [J].