Functionalized macrocyclic ligands: Big building blocks for metal coordination

被引:42
作者
Campbell, K [1 ]
McDonald, R [1 ]
Ferguson, MJ [1 ]
Tykwinski, RR [1 ]
机构
[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada
关键词
D O I
10.1021/om020738k
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two large, conjugated, macrocyclic ligands, 5a and 5b, have been efficiently prepared from easily accessible precursors. Both macrocycles incorporate a 3,5-diethynylpyridine subunit, making them suitable for further elaboration, as demonstrated via their coordination to give Pt complexes 6a and 6b.
引用
收藏
页码:1353 / 1355
页数:3
相关论文
共 44 条
[1]   Synthesis of neutral tetranuclear and octanuclear macrocyclic platinum-butadiyne heterocyclynes [J].
ALQaisi, SM ;
Galat, KJ ;
Chai, MH ;
Ray, DG ;
Rinaldi, PL ;
Tessier, CA ;
Youngs, WJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (46) :12149-12150
[2]   Quantitative formation of coordination nanotubes templated by rodlike guests [J].
Aoyagi, M ;
Biradha, K ;
Fujita, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (32) :7457-7458
[3]   Pd(II)- and Pt(II)-linked tetranuclear complexes as assembly units for higher ordered structures [J].
Aoyagi, M ;
Biradha, K ;
Fujita, M .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1999, 72 (12) :2603-2606
[4]  
Baxter PNW, 2002, CHEM-EUR J, V8, P5250, DOI 10.1002/1521-3765(20021115)8:22<5250::AID-CHEM5250>3.0.CO
[5]  
2-Q
[6]   Synthesis and crystallographic characterization of a novel platinocycle [J].
Bosch, E ;
Barnes, CL .
ORGANOMETALLICS, 2000, 19 (25) :5522-5524
[7]   Coordination-driven self-assembly: Solids with bidirectional porosity [J].
Campbell, K ;
Kuehl, CJ ;
Ferguson, MJ ;
Stang, PJ ;
Tykwinski, RR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (25) :7266-7267
[8]   Rigid, cross-conjugated macrocycles:: A cyclic alternative to 4,4′-bipyridines in supramolecular chemistry [J].
Campbell, K ;
McDonald, R ;
Branda, NR ;
Tykwinski, RR .
ORGANIC LETTERS, 2001, 3 (07) :1045-1048
[9]   Functionalized macrocyclic ligands for use in supramolecular chemistry [J].
Campbell, K ;
McDonald, R ;
Tykwinski, RR .
JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (04) :1133-1140
[10]  
CAMPBELL K, UNPUB