Swelling behavior of interpenetrating polymer network hydrogels composed of poly(vinyl alcohol) and chitosan

被引:223
作者
Kim, SJ [1 ]
Park, SJ [1 ]
Kim, SI [1 ]
机构
[1] Hanyang Univ, Dept Biomed Engn, Seoul 133605, South Korea
关键词
interpenetrating polymer network; poly(vinyl alcohol); chitosan; swelling;
D O I
10.1016/S1381-5148(02)00214-6
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Interpenetrating polymer network (IPN) hydrogels composed of poly(vinyl alcohol) (PVA) and chitosan were prepared by UV irradiation. The characteristics of IPN hydrogels were investigated by swelling experiments, Fourier transform infrared (FT-IR) spectroscopy and differential scanning calorimetry (DSC). IPN hydrogels exhibited a relatively high swelling ratio in the range of 210-350% at 35 degreesC. The swelling ratio of PVA/chitosan IPN hydrogels depended on pH and temperature. DSC was used for the quantitative determination of the amounts of freezing and non-freezing water. Free water contents in IPN1, IPN2 and IPN3 were 62.0, 69.6 and 72.3% in pure water, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:53 / 59
页数:7
相关论文
共 31 条
[1]  
ALBIN G, 1985, Journal of Controlled Release, V2, P153, DOI 10.1016/0168-3659(85)90041-0
[2]  
[Anonymous], BIOCOMPATIBILITY CLI
[3]   TEMPERATURE-RESPONSIVE INTERPENETRATING POLYMER NETWORKS CONSTRUCTED WITH POLY(ACRYLIC ACID) AND POLY(N,N-DIMETHYLACRYLAMIDE) [J].
AOKI, T ;
KAWASHIMA, M ;
KATONO, H ;
SANUI, K ;
OGATA, N ;
OKANO, T ;
SAKURAI, Y .
MACROMOLECULES, 1994, 27 (04) :947-952
[4]   PH-SENSITIVE MEMBRANES FROM POLY(VINYL ALCOHOL) POLY(ACRYLIC ACID) INTERPENETRATING NETWORKS [J].
GUDEMAN, LF ;
PEPPAS, NA .
JOURNAL OF MEMBRANE SCIENCE, 1995, 107 (03) :239-248
[5]   PREPARATION AND CHARACTERIZATION OF PH-SENSITIVE, INTERPENETRATING NETWORKS OF POLY(VINYL ALCOHOL) AND POLY(ACRYLIC ACID) [J].
GUDEMAN, LF ;
PEPPAS, NA .
JOURNAL OF APPLIED POLYMER SCIENCE, 1995, 55 (06) :919-928
[6]   RELEASE OF INSULIN FROM PH-SENSITIVE POLY(ORTHO ESTERS) [J].
HELLER, J ;
CHANG, AC ;
RODD, G ;
GRODSKY, GM .
JOURNAL OF CONTROLLED RELEASE, 1990, 13 (2-3) :295-302
[7]   VOLUME PHASE-TRANSITION IN A NONIONIC GEL [J].
HIROKAWA, Y ;
TANAKA, T .
JOURNAL OF CHEMICAL PHYSICS, 1984, 81 (12) :6379-6380
[8]   CHANGE IN MICRO-ENVIRONMENTS IN POLY(ACRYLAMIDE) GEL WITH PYRENYL PROBE DUE TO ITS VOLUME PHASE-TRANSITION INDUCED BY PH CHANGE [J].
HU, YX ;
HORIE, K ;
TORII, T ;
USHIKI, H ;
TANG, XY .
POLYMER JOURNAL, 1993, 25 (02) :123-130
[9]   SYNTHESIS AND PROPERTIES OF SEMIINTERPENETRATING POLYMER NETWORKS COMPOSED OF BETA-CHITIN AND POLY(ETHYLENE GLYCOL) MACROMER [J].
KIM, SS ;
LEE, YM ;
CHO, CS .
POLYMER, 1995, 36 (23) :4497-4501
[10]   SEMIINTERPENETRATING POLYMER NETWORKS COMPOSED OF BETA-CHITIN AND POLY(ETHYLENE GLYCOL) MACROMER [J].
KIM, SS ;
LEE, YM ;
CHO, CS .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1995, 33 (13) :2285-2287