Understanding the influence of active (zeolite) and passive (polyethylene) reaction cages on photo-claisen rearrangements of aryl benzyl ethers

被引：25

作者：

Gu, WQ

Warrier, M

Schoon, B

Ramamurthy, V

Weiss, RG ^{[1
]}

机构：

[1] Tulane Univ, New Orleans, LA 70118 USA

[2] Georgetown Univ, Dept Chem, Washington, DC 20057 USA

来源：

LANGMUIR | 2000年 / 16卷 / 17期

关键词：

D O I：

10.1021/la000574h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photo-Claisen rearrangements of benzyl phenyl ether and benzyl l-naphthyl ether have been examined in cation-exchanged Y zeolites and polyethylenes of differing crystallinities. Ratios of the principal rearrangement products, benzyl arylol positional isomers, indicate that the reactions are more selective in the zeolites than in the polyethylenes. The results are explained on the basis of the active and passive walls of the reaction cages of zeolites and polyethylenes, respectively, and the limited free volume of the polyethylene cages.

引用

页码：6977 / 6981

页数：5

共 26 条

[1] CIDNP EVIDENCE FOR DIVERGENT BEHAVIOR OF SINGLET AND TRIPLET RADICAL PAIR ENCOUNTERS IN PHOTO-CLAISEN REARRANGEMENT [J].