Evidence for the formation of terminal hydrides by protonation of an asymmetric iron hydrogenase active site mimic

被引：193

作者：

Ezzaher, Salah ^{[1
]}

Capon, Jean-Francois ^{[1
]}

Gloaguen, Frederic ^{[1
]}

Petillon, Francois Y. ^{[1
]}

Schollhammer, Philippe ^{[1
]}

Talarmin, Jean ^{[1
]}

机构：

[1] Univ Bretagne Occidentale, CNRS, UMR 6521, Fac Sci, F-29238 Brest 3, France

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 09期

关键词：

D O I：

10.1021/ic0703124

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of [Fe-2(mu-pdt)(CO)(6)] [pdt = S(CH2)(3)S] with dppe (Ph2PCH2CH2PPh2) in refluxing toluene affords the asymmetric complex [Fe-2(mu-pdt)(CO)(4)(dppe)] (1). Protonation of 1 with HBF4-Et2O in CH2Cl2 gives at room temperature the mu-hydrido derivative [Fe-2(mu-pdt)(CO)(4)(dppe)(mu-H)](BF4) (2). Monitoring the reaction by H-1, P-31, and C-13 NMR at low temperature reveals unambiguously that the process of the protonation of 1 implies terminal hydride intermediates.

引用

页码：3426 / 3428

页数：3

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