New polymer-supported phosphonate reagents for the synthesis of Z-α,β-unsaturated esters

被引：12

作者：

Ando, Kaori ^{[1
]}

Suzuki, Yusaku ^{[1
]}

机构：

[1] Gifu Univ, Fac Engn, Dept Chem, Gifu 5011193, Japan

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 17期

关键词：

WADSWORTH-EMMONS REACTION; Z-UNSATURATED ESTERS; SOLID-PHASE SYNTHESIS; ETHYL (DIARYLPHOSPHONO)ACETATES; SELECTIVE SYNTHESIS; ORGANIC-SYNTHESIS; PURIFICATION; OLEFINATION; ALDEHYDES; AMIDES;

D O I：

10.1016/j.tetlet.2010.02.113

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New polymer-supported phosphonate reagents have been prepared and evaluated for the synthesis of Z-alpha,beta-unsaturated esters. High Z-selectivity was obtained using the reagent having two o-t-BuC(6)H(4) groups. (C) 2010 Elsevier Ltd. All rights reserved.

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页码：2323 / 2325

页数：3

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