Reaction of diisobutylaluminium hydride with selenium and tellurium: new reagents for the synthesis of seleno- and telluro-amides

被引：38

作者：

Li, GM ^{[1
]}

Zingaro, RA ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 04期

关键词：

D O I：

10.1039/a707792k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diisobutylaluminium hydride ((Bu2AlH)-Al-i) undergoes reaction with elemental selenium and tellurium to afford new reagents having an Al-Se or an Al-Te bond, These directly convert amides to selenoamides and telluroformamides. This affords a one-pot route to selenoamides and telluroformamides starting from Se and Te, and may be suitable for large scale syntheses.

引用

页码：647 / 650

页数：4

共 23 条

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