Effective adsorption of chlorophyll a by FSM-type mesoporous silica modified with 1,4-butanediol

被引:35
作者
Murata, S
Hata, H
Kimura, T
Sugahara, Y
Kuroda, K
机构
[1] Waseda Univ, Dept Appl Chem, Shinjuku Ku, Tokyo 1698555, Japan
[2] Waseda Univ, Kagami Mem Lab Mat Sci & Technol, Shinjuku Ku, Tokyo 1690051, Japan
关键词
D O I
10.1021/la991393m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Surface silanol groups of FSM-type mesoporous silica were modified with 1,4-butanediol, and the esterified material was successfully used as the adsorbent to accommodate chlorophyll alpha molecules. Pheophytinization was effectively suppressed by the presence of the surface organic groups grafted onto the mesoporous silica, whereas pheophytinization occurred in unmodified mesoporous silica.
引用
收藏
页码:7106 / 7108
页数:3
相关论文
共 27 条
[1]  
ABRAHAM RJ, 1991, CHLOROPHYLLS
[2]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[3]   Catalysis of liquid phase organic reactions using chemically modified mesoporous inorganic solids [J].
Clark, JH ;
Macquarrie, DJ .
CHEMICAL COMMUNICATIONS, 1998, (08) :853-860
[4]   From microporous to mesoporous molecular sieve materials and their use in catalysis [J].
Corma, A .
CHEMICAL REVIEWS, 1997, 97 (06) :2373-2419
[5]   Synthesis and characterization of cobalt-complex functionalized MCM-41. [J].
Diaz, JF ;
Balkus, KJ ;
Bedioui, F ;
Kurshev, V ;
Kevan, L .
CHEMISTRY OF MATERIALS, 1997, 9 (01) :61-67
[6]   Functionalized monolayers on ordered mesoporous supports [J].
Feng, X ;
Fryxell, GE ;
Wang, LQ ;
Kim, AY ;
Liu, J ;
Kemner, KM .
SCIENCE, 1997, 276 (5314) :923-926
[7]   Adsorption of taxol into ordered mesoporous silicas with various pore diameters [J].
Hata, H ;
Saeki, S ;
Kimura, T ;
Sugahara, Y ;
Kuroda, K .
CHEMISTRY OF MATERIALS, 1999, 11 (04) :1110-1119
[8]   Encapsulation, stabilization, and catalytic properties of flexible metal porphyrin complexes in MCM-41 with minimal electronic perturbation by the environment [J].
Holland, BT ;
Walkup, C ;
Stein, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (22) :4301-4309
[9]   METHOD FOR THE CALCULATION OF EFFECTIVE PORE-SIZE DISTRIBUTION IN MOLECULAR-SIEVE CARBON [J].
HORVATH, G ;
KAWAZOE, K .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1983, 16 (06) :470-475
[10]   Syntheses of highly ordered mesoporous materials, FSM-16, derived from kanemite [J].
Inagaki, S ;
Koiwai, A ;
Suzuki, N ;
Fukushima, Y ;
Kuroda, K .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (05) :1449-1457