Polyaniline on surface modification of diatomite: a novel way to obtain conducting diatomite fillers

被引：63

作者：

Li, XW ^{[1
]}

Bian, CQ ^{[1
]}

Chen, W ^{[1
]}

He, JB ^{[1
]}

Wang, ZQ ^{[1
]}

Xu, N ^{[1
]}

Xue, G ^{[1
]}

机构：

[1] Nanjing Univ, Dept Polymer Sci & Engn, Nanjing 210093, Peoples R China

来源：

APPLIED SURFACE SCIENCE | 2003年 / 207卷 / 1-4期

基金：

中国国家自然科学基金;

关键词：

polyaniline; diatomite; interface;

D O I：

10.1016/S0169-4332(03)00010-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A conducting diatomite was obtained by polyaniline on surface modification of diatomite, and was characterized via Fourier-transform Raman spectra, UV-Vis absorption spectra, thermogravimetric analysis and scanning electron microscope, as well as conductivity. The results of spectroanalysis illustrate that polyaniline is not simply blended with diatomite. An interaction exists at the interface of diatomite and polyaniline, which may associate with hydrogen bond formed between the surface of diatomite with electronegativity and N-H bond in polyaniline macromolecule. The results of thermogravimetric analysis suggest that the conducting diatomite only contains 8% polyaniline by mass, but its conductivity has reached 2.8 x 10(-2) S cm(-1) at 20 degreesC. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：378 / 383

页数：6

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