Tailored synthesis of structurally defined polymers by organotellurium-mediated living radical polymerization (TERP): Synthesis of poly(meth)acrylate derivatives and their Di- and triblock copolymers

被引:166
作者
Yamago, S [1 ]
Lida, K [1 ]
Yoshida, J [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Sakyo Ku, Kyoto 6068501, Japan
关键词
D O I
10.1021/ja027599i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The organotellurium-mediated living radical polymerization (TERP) method allows the synthesis of various polyacrylate and polymethacrylate derivatives with precise control of molecular weight and with defined end groups. The method can be applied to the synthesis of AB-diblock and ABA- and ABC-triblock copolymers composed of different families of monomers. Copyright © 2002 American Chemical Society.
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页码:13666 / 13667
页数:2
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