Genetic algorithm-assisted combinatorial search for new red phosphors of high efficiency at soft ultraviolet excitation

被引:17
作者
Sohn, KS [1 ]
Kim, BI
Shin, N
机构
[1] Sunchon Natl Univ, Dept Met Engn & Mat Sci, Chonam 540742, South Korea
[2] Pohang Accelerator Lab, Beamline Div, Kyungbuk 790784, South Korea
关键词
D O I
10.1149/1.1808592
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We developed an evolutionary optimization process involving a genetic algorithm and combinatorial chemistry (combi-chem), which was tailored exclusively for the development of light emitting diode (LED) phosphors with a high luminescent efficiency, when excited by soft ultraviolet irradiation. The ultimate goal of our study was to develop oxide red phosphors, which are suitable for three-band white LEDs. To accomplish this, a computational evolutionary optimization process was adopted to screen a Eu3+-doped alkali earth borosilicate system. The genetic algorithm is a well-known, very efficient heuristic optimization method and combi-chem is also a powerful tool for use in an actual experimental optimization process. Therefore the combination of a genetic algorithm and combi-chem would enhance the searching efficiency when applied to phosphor screening. Vertical simulations and an actual synthesis were carried out and promising red phosphors for three-band white LED applications were obtained. (C) 2004 The Electrochemical Society.
引用
收藏
页码:H243 / H248
页数:6
相关论文
共 25 条
[1]   A CLASS OF COBALT OXIDE MAGNETORESISTANCE MATERIALS DISCOVERED WITH COMBINATORIAL SYNTHESIS [J].
BRICENO, G ;
CHANG, HY ;
SUN, XD ;
SCHULTZ, PG ;
XIANG, XD .
SCIENCE, 1995, 270 (5234) :273-275
[2]   THE COMBINATORIAL SYNTHESIS AND CHEMICAL AND BIOLOGICAL EVALUATION OF A 1,4-BENZODIAZEPINE LIBRARY [J].
BUNIN, BA ;
PLUNKETT, MJ ;
ELLMAN, JA .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1994, 91 (11) :4708-4712
[3]   Computational methods in molecular diversity and combinatorial chemistry [J].
Bures, MG ;
Martin, YC .
CURRENT OPINION IN CHEMICAL BIOLOGY, 1998, 2 (03) :376-380
[4]   Fundamental and combinatorial approaches in the search for and optimisation of catalytic materials for the oxidative dehydrogenation of propane to propene [J].
Buyevskaya, OV ;
Brückner, A ;
Kondratenko, EV ;
Wolf, D ;
Baerns, M .
CATALYSIS TODAY, 2001, 67 (04) :369-378
[5]   A combinatorial approach to the discovery and optimization of luminescent materials [J].
Danielson, E ;
Golden, JH ;
McFarland, EW ;
Reaves, CM ;
Weinberg, WH ;
Wu, XD .
NATURE, 1997, 389 (6654) :944-948
[6]   A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods [J].
Danielson, E ;
Devenney, M ;
Giaquinta, DM ;
Golden, JH ;
Haushalter, RC ;
McFarland, EW ;
Poojary, DM ;
Reaves, CM ;
Weinberg, WH ;
Wu, XD .
SCIENCE, 1998, 279 (5352) :837-839
[7]   Combinatorial library design using a multiobjective genetic algorithm [J].
Gillet, VJ ;
Khatib, W ;
Willett, P ;
Fleming, PJ ;
Green, DVS .
JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES, 2002, 42 (02) :375-385
[8]   Optical properties of three-band white light emitting diodes [J].
Huh, YD ;
Shim, JH ;
Kim, Y ;
Do, YR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (02) :H57-H60
[9]  
KIM CH, 2002, J ELECTROCHEM SOC, V149, pH21
[10]  
NARISADA K, 2000, PHOSPHOR HDB, pCH17