A simple route towards magnetically modified zeolites

被引:60
作者
Bourlinos, AB
Zboril, R
Petridis, D
机构
[1] NCSR Demokritos, Inst Mat Sci, GR-15310 Athens, Greece
[2] Palacky Univ, Dept Inorgan & Phys Chem, CR-77147 Olomouc, Czech Republic
关键词
carboxylic acid vapor treatment; iron(III) containing zeolite Y; maghemite; magnetically modified zeolite Y; melt exchange reactions;
D O I
10.1016/S1387-1811(02)00613-3
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A simple route for decorating the external surfaces of zeolites with maghemite. nanoparticles is described. The synthesis comprises feeding of a zeolite support with different amounts of iron(III) by employing melt exchange reactions, exposure of the iron-containing solids to vapors of formic acid and finally calcination of the resulting derivatives in air to afford maghemite nanoparticles embedded in the zeolite host. The as-prepared magnetically modified solids, characterized by XRD, Mossbauer and magnetic measurements and SEM and TEM techniques, were found to retain the cation exchange capacity of the parent zeolite as well as its structural integrity. (C) 2002 Elsevier Science Inc. All rights reserved.
引用
收藏
页码:155 / 162
页数:8
相关论文
共 26 条
[1]  
Bourlinos A, 2001, ADV MATER, V13, P289, DOI 10.1002/1521-4095(200102)13:4<289::AID-ADMA289>3.0.CO
[2]  
2-U
[3]  
BOURLINOS A, UNPUB, P4
[4]   Synthesis and characterization of magnetically modified clay composites [J].
Bourlinos, AB ;
Karakassides, MA ;
Simopoulos, A ;
Petridis, D .
CHEMISTRY OF MATERIALS, 2000, 12 (09) :2640-2645
[5]   Magnetic modification of the external surfaces in the MCM-41 porous silica: Synthesis, characterization, and functionalization [J].
Bourlinos, AB ;
Simopoulos, A ;
Boukos, N ;
Petridis, D .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (31) :7432-7437
[6]  
Breck DW, 1974, ZEOLITES MOL SIEVES
[7]   MICROPORES AND MICROPERMEABLE TEXTURE IN ALKALI FELDSPARS - GEOCHEMICAL AND GEOPHYSICAL IMPLICATIONS [J].
DAVID, F ;
WALKER, FDL ;
LEE, MR ;
PARSONS, I .
MINERALOGICAL MAGAZINE, 1995, 59 (396) :505-534
[8]  
DYER A, 1988, ZEOLITES MOL SIEVES
[9]   INTRAZEOLITE SYNTHESIS OF POLYTHIOPHENE CHAINS [J].
ENZEL, P ;
BEIN, T .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (18) :1326-1327
[10]   MOSSBAUER STUDIES OF SMALL PARTICLES OF IRON OXIDES IN SOIL [J].
GANGAS, NH ;
SIMOPOULOS, A ;
KOSTIKAS, A ;
YASSOGLOU, NJ ;
FILIPPAKIS, S .
CLAYS AND CLAY MINERALS, 1973, 21 (03) :151-160