Synthesis of Precision Ionic Polyolefins Derived from Ionic Liquids

被引：54

作者：

Aitken, Brian S. ^{[1
]}

Lee, Minjae ^{[2
]}

Hunley, Matthew T. ^{[2
]}

Gibson, Harry W. ^{[2
]}

Wagener, Kenneth B. ^{[1
]}

机构：

[1] Univ Florida, George & Josephine Butler Polymer Res Lab, Dept Chem, Gainesville, FL 32611 USA

[2] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24061 USA

来源：

MACROMOLECULES | 2010年 / 43卷 / 04期

关键词：

ETHYLENE/METHACRYLIC ACID IONOMERS; MECHANICAL RELAXATIONS; POLYMER ELECTROLYTES; CONDUCTIVITY; PERCOLATION; METATHESIS; COPOLYMERS; MORPHOLOGY; TRANSPORT; ETHYLENE;

D O I：

10.1021/ma9024174

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of ionic polyolefins derived from ionic liquid (IL) monomers with the use of acyclic diene metathesis polymerization was anzlyzed. The metathesis polycondensation of a fully ionic monomer was accomplished by preparing ionic monomers that are liquids thus allowed for bulk polymerization. The concentration of phosphoric acid was varied from 1 to 25 mol % with respect to monomer and olefin isomerization was effectively ceased with the addition of 10 mol % acid. Dynamic mechanical analysis (DMA) data, in tensile geometry, was collected on melt pressed films, information which clearly specifies the mechanical differences between the in-chain material and the pendant polymer. The regioregular ionic polymers exhibited a high degree of interchain interaction between precisely placed ionic functionalities, supported by both persistent aggregation of the polymers in a wide variety of organic solvents and their mechanical behaviors.

引用

页码：1699 / 1701

页数：3

共 36 条

[1] Ionic thermoplastic elastomers: A review [J].

Antony, P ;

De, SK .

JOURNAL OF MACROMOLECULAR SCIENCE-POLYMER REVIEWS, 2001, C41 (1-2) :41-77

[2] Synthesis and morphology of well-defined poly(ethylene-co-acrylic acid) copolymers [J].

Baughman, Travis W. ;

Chan, Christopher D. ;

Winey, Karen I. ;

Wagener, Kenneth B. .

MACROMOLECULES, 2007, 40 (18) :6564-6571

[3] Recent advances in ADMET polymerization [J].

Baughman, TW ;

Wagener, KB .

METATHESIS POLYMERIZATION, 2005, 176 :1-42

[4] MICROSCOPIC INVESTIGATION OF IONIC-CONDUCTIVITY IN ALKALI-METAL SALTS POLY(ETHYLENE OXIDE) ADDUCTS [J].

BERTHIER, C ;

GORECKI, W ;

MINIER, M ;

ARMAND, MB ;

CHABAGNO, JM ;

RIGAUD, P .

SOLID STATE IONICS, 1983, 11 (01) :91-95

[5] Nature and properties of ionomer assemblies. II [J].

Capek, I .

ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2005, 118 (1-3) :73-112

[6] Dispersions of polymer ionomers: I [J].

Capek, I .

ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2004, 112 (1-3) :1-29

[7] POLYMERIC SOLID ELECTROLYTES - DYNAMIC BOND PERCOLATION AND FREE-VOLUME MODELS FOR DIFFUSION [J].

DRUGER, SD ;

RATNER, MA ;

NITZAN, A .

SOLID STATE IONICS, 1983, 9-10 (DEC) :1115-1120

[8]

Eisenberg A., 1977, ION CONTAINING POLYM

[9]

Eisenberg A., 1998, Introduction to Ionomers, VFirst

[10] Ionic conductivity in crystalline polymer electrolytes [J].

Gadjourova, Z ;

Andreev, YG ;

Tunstall, DP ;

Bruce, PG .

NATURE, 2001, 412 (6846) :520-523

← 1 2 3 4 →