NMR spectroscopic correlations for a series of triangular α-oxoruthenium acetate clusters containing substituted pyridine ligands

被引：29

作者：

Alexiou, ADP ^{[1
]}

Toma, HE ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim, BR-05599970 Sao Paulo, Brazil

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 1997年 / 09期

关键词：

D O I：

10.1039/a701058c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The H-1 and C-13 NMR chemical shifts of the acetate and pyridine ligands (alpha-position) in a series of [RU3O(CH3CO2)(6)L-3](+) clusters are linearly correlated with the pK(8) (L), but exhibit variable trends at the various positions as a consequence of the inductive, paramagnetic anisotropy and ring current effects and the ligand interactions through the Ru3O core.

引用

页码：338 / 339

页数：3

共 20 条

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