New simple and inexpensive synthetic route, mediated by sulfur, to enantiopure (-)-conduritol E derivative from D-mannitol.

被引：20

作者：

Cere, V

Peri, F

Pollicino, S

机构：

[1] Dept. Organ. Chemistry A. Mangini, I-40136 Bologna, Viale Risorgimento

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 44期

关键词：

D O I：

10.1016/S0040-4039(97)10040-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We have synthesized a (-)-Conduritol E derivative, enantiomerically pure, using as starting material D-mannitol. This latter, possessing already the same configuration of the expected product at the four chiral carbon atoms, was subjected to reaction to form a cyclic unsaturated polyhydroxylated compound, preserving the configuration at all chiral carbon atoms of the sugar. (C) 1997 Elsevier Science Ltd.

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页码：7797 / 7800

页数：4

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