1,n-dicarbanionic titanium intermediates from monocarbanionic organometallics and their application in organic synthesis

被引：421

作者：

Kulinkovich, OG

de Meijere, A

机构：

[1] Belarusian State Univ, Dept Chem, Minsk 220050, BELARUS

[2] Univ Gottingen, Inst Organ Chem, D-37077 Gottingen, Germany

来源：

CHEMICAL REVIEWS | 2000年 / 100卷 / 08期

关键词：

D O I：

10.1021/cr980046z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Low-valent titanium species, generated by reduction of titanium(IV) derivatives, can act as precursors to reagents which are either 1,1-, 1,2-, 1,3-, or even 1,4-dicarbanionic synthesis equivalents. To date, the most synthetic progress has been made with the synthetic applications of 1,2-dicarbanionic titanium intermediates generated from titanium tetraalkoxides and Grignard reagents.

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页码：2789 / 2834

页数：46

相关论文

共 378 条

[1] Enantioselective syntheses of a 1 alpha-hydroxyvitamin D ring A precursor from 3-(triphenylsilyl)glycidol and from malic acid [J].

Achmatowicz, B ;

Jankowski, P ;

Wicha, J .

TETRAHEDRON LETTERS, 1996, 37 (31) :5589-5592

[2]

AGER DJ, 1984, SYNTHESIS-STUTTGART, P384

[3]

AKEMOTO Y, 1998, J CHEM SOC CHEM COMM, P651

[4] CHEMICAL BONDING AND REACTIVITY IN NICKEL-ETHENE COMPLEXES - ABINITIO MO-SCF STUDY [J].

AKERMARK, B ;

ALMEMARK, M ;

ALMLOF, J ;

BACKVALL, JE ;

ROOS, B ;

STOGARD, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (14) :4617-4624

[5] HIGHLY STEREOSELECTIVE ISOMERIZATION OF MONOSUBSTITUTED 1-ALKENES TO (E)-2-ALKENES BY CATALYSIS OF (C5ME5)2TICL2/NAC10H8 [J].

AKITA, M ;

YASUDA, H ;

NAGASUNA, K ;

NAKAMURA, A .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1983, 56 (02) :554-558

[6] ETHYLENE COMPLEXES - BONDING, ROTATIONAL BARRIERS, AND CONFORMATIONAL PREFERENCES [J].

ALBRIGHT, TA ;

HOFFMANN, R ;

THIBEAULT, JC ;

THORN, DL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (14) :3801-3812

[7] A simple and efficient hydrodehalogenation of 1,1-dihalocyclopropanes [J].

AlDulayymi, JR ;

Baird, MS ;

Bolesov, IG ;

Tveresovsky, V ;

Rubin, M .

TETRAHEDRON LETTERS, 1996, 37 (49) :8933-8936

[8] FORMATION AND REACTIVITY OF THE ETHYLENE COMPLEX CP2TIC2H4 - THE CRYSTAL-STRUCTURE OF (CP2TIET)2O [J].

ALT, HG ;

SCHWIND, KH ;

RAUSCH, MD ;

THEWALT, U .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 349 (1-2) :C7-C10

[9] AUTOMATED THERMAL-DEGRADATION STUDIES ON SOLID SIGMA-ORGANOTRANSITION METAL-COMPLEXES - DIMETHYL-TITANOCENE, DIMETHYL-ZIRCONOCENE AND DIMETHYL-HAFNOCENE [J].

ALT, HG ;

DISANZO, FP ;

RAUSCH, MD ;

UDEN, PC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 107 (02) :257-263

[10]

[Anonymous], ADV STR ORG

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