Synthesis and characterization of aromatic block copolyamides by condensative chain polymerization

被引：6

作者：

Ohshimizu, Kaoru

Shibasaki, Yuji

Komura, Motonori

Nakajima, Ken

Ueda, Mitsuru ^{[1
]}

机构：

[1] Grad Sch Sci & Engn, Tokyo Inst Technol, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 152, Japan

[2] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

CHEMISTRY LETTERS | 2007年 / 36卷 / 06期

关键词：

D O I：

10.1246/cl.2007.742

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aromatic block copolyamides with well-controlled molecular weights (MWs) and narrow polydispersities (PDIs) were successfully prepared by the condensative chain polymerization of 3-[4-(N-octylamino)benzoyl]benzoxazoline-2-thione (1) and 3-[4-(N-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorooetylamino)benzoyl]benzoxazoline-2-thione (2). The formation of the block copolymers was confirmed by GPC, DSC, and NMR analyses. The thin film formed on mica was analyzed using atomic force microscopy (AFM), and the results indicated the existence of phase segregation.

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页码：742 / 743

页数：2

相关论文

共 9 条

[1] Experimental evidence for the quasi-"living" nature of the grignard metathesis method for the synthesis of regioregular poly(3-alkylthiophenes) [J].

Iovu, MC ;

Sheina, EE ;

Gil, RR ;

McCullough, RD .

MACROMOLECULES, 2005, 38 (21) :8649-8656

[2] Catalyst-transfer polycondensation for the synthesis of poly(p-phenylene) with controlled molecular weight and low polydispersity [J].

Miyakoshi, Ryo ;

Shimono, Kyohei ;

Yokoyama, Akihiro ;

Yokozawa, Tsutomu .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (50) :16012-16013

[3]

OHSHIMIZU K, UNPUB POLYM J

[4] Control of molecular weight distribution in polycondensation polymers 2. Poly(ether ketone) synthesis [J].

Shibasaki, Y ;

Araki, T ;

Nagahata, R ;

Ueda, M .

EUROPEAN POLYMER JOURNAL, 2005, 41 (10) :2428-2433

[5] Control of molecular weight distribution in polycondensation polymers. Polyamide synthesis [J].

Shibasaki, Y ;

Araki, T ;

Okazaki, M ;

Ueda, M .

POLYMER JOURNAL, 2002, 34 (04) :261-266

[6] Chain-growth polycondensation for aromatic polyethers with low polydispersities: Living polymerization nature in polycondensation [J].

Suzuki, Y ;

Hiraoka, S ;

Yokoyama, A ;

Yokozawa, T .

MACROMOLECULES, 2003, 36 (13) :4756-4765

[7] Chain-growth polycondensation for well-defined aramide. Synthesis of unprecedented block copolymer containing aramide with low polydispersity [J].

Yokozawa, T ;

Ogawa, M ;

Sekino, A ;

Sugi, R ;

Yokoyama, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (51) :15158-15159

[8] Chain-growth polycondensation of monomer consisting of two aromatic rings: Synthesis of well-defined poly(ether sulfone) from 4-fluoro-4'hydroxydiphenyl sulfone [J].

Yokozawa, T ;

Taniguchi, T ;

Suzuki, Y ;

Yokoyama, A .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (20) :3460-3464

[9] Chain-growth polycondensation: The living polymerization process in polycondensation [J].

Yokozawa, Tsutomu ;

Yokoyama, Akihiro .

PROGRESS IN POLYMER SCIENCE, 2007, 32 (01) :147-172