A selective conversion of sulfide to sulfoxide in hexafluoro-2-propanol

被引:105
作者
Ravikumar, KS [1 ]
Bégué, JP [1 ]
Bonnet-Delpon, D [1 ]
机构
[1] CNRS, Ctr Etud Pharmaceut, Lab BIOCIS, F-92296 Chatenay Malabry, France
关键词
fluorine and compounds; oxidation; solvents and solvent effects; sulfoxides;
D O I
10.1016/S0040-4039(98)00498-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A facile, selective and efficient method for the oxidation of sulfides to sulfoxides by aqueous 30% H2O2 in hexafluoro-2-propanol at room temperature is described. Specific role of the solvent in the selectivity is exhibited. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3141 / 3144
页数:4
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