Synthesis and characterization of metal containing polyurethanes and polyurethane-ureas based on new divalent metal salts of mono(hydroxybutyl)phthalate

被引：18

作者：

Prasath, RA ^{[1
]}

Nanjundan, S ^{[1
]}

机构：

[1] Anna Univ, Coll Engn, Dept Chem, Madras 600025, Tamil Nadu, India

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 1998年 / A35卷 / 05期

关键词：

divalent metal salts of mono(hydroxybutyl)phthalate; ionic monomers; polyurethane; polyurethane-ureas; spectral studies; viscosity; and thermogravimetric analysis;

D O I：

10.1080/10601329808002014

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Divalent metal salts of mono(hydroxybutyl)phthalate were synthesized by the addition of 1,4-butane diol, phthalic anhydride and divalent metal [Ca2+, Mn2+ and Pb2+] acetates. A series of metal containing polyurethane and polyurethane-ureas containing ionic links in the main chain were synthesized by the polyaddition reaction of hexamethylene diisocyanate (HMDI) or toluylene 2,4-diisocyanate (TDI) with divalent metal salts of mono(hydroxybutyl)phthalate [M(HBP)(2)] and 1:1 mixtures of toluylene 2,4-bis(omega,N-hydroxyethylurea) [TBHEU] and M(HBP)(2). M(HBP)(2) and the polymers were characterized by elemental analysis, solubility, viscosity, spectral studies (IR and FT NMR) and thermogravimetric analysis (TGA).

引用

页码：821 / 842

页数：22

共 28 条

[1] NEW METALLOPORPHYRIN CONTAINING POLYMERS FROM THE HECK COUPLING REACTION [J].

BAO, ZN ;

CHEN, YM ;

YU, LP .

MACROMOLECULES, 1994, 27 (16) :4629-4631

[2]

DURAIRAJ B, 1979, POLYM BULL, V1, P723

[3] SYNTHESIS OF SOME NEW METAL-CONTAINING POLYURETHANES [J].

DURAIRAJ, B ;

RAO, KV .

EUROPEAN POLYMER JOURNAL, 1980, 16 (10) :941-944

[4] Synthesis and characterization of a conjugated copolymer of poly(phenylenevinylene) containing a metalloporphyrin incorporated into the polymer backbone [J].

Jiang, BW ;

Jones, WE .

MACROMOLECULES, 1997, 30 (19) :5575-5581

[5]

KOTHANDARAMAN H, 1985, POLYM BULL, V13, P353

[6] Synthesis of organometallic polymers containing cobaltacyclopentadiene moieties in the main chain. Synthesis of organocobalt polymers from various diynes [J].

Lee, JC ;

Nishio, A ;

Tomita, I ;

Endo, T .

MACROMOLECULES, 1997, 30 (18) :5205-5212

[7]

LIPATOVA TE, 1970, VYSOKOMOL SOEDIN A, V12, P911

[8] SYNTHESES AND PROPERTIES OF HALATO-TELECHELIC POLYURETHANE-UREAS FROM DIVALENT METAL-SALTS OF P-AMINOBENZOIC ACID, DIAMINE, DIALKYLENE GLYCOLS, AND DIISOCYANATE [J].

MATSUDA, H ;

TAKECHI, S .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1991, 29 (01) :83-91

[9] SYNTHESIS OF POLYMERS BY USING DIVALENT METAL-SALTS OF MONO(HYDROXYETHYL) PHTHALATE - METAL-CONTAINING POLYURETHANES [J].

MATSUDA, H .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1974, 12 (02) :455-468

[10] STABILITY, CURE PROPERTIES, AND APPLICABILITY AS ONE PART ADHESIVES OF SYSTEMS OF DIVALENT METAL-SALTS OF MONO(HYDROXYETHYL) PHTHALATE ANHYDRIDE BISEPOXIDE [J].

MATSUDA, H ;

KANAOKA, K .

JOURNAL OF APPLIED POLYMER SCIENCE, 1985, 30 (03) :1229-1239

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