Electrochemical crystallization of cuprous oxide with systematic shape evolution

被引:402
作者
Siegfried, MJ [1 ]
Choi, KS [1 ]
机构
[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA
关键词
D O I
10.1002/adma.200400177
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The growth Of Cu2O crystals that are electrochemically deposited as micrometer-size crystals with systematically varying fractions of {100} and {111} faces is reported (the Figure depicts cubic crystals). The methodical and homogeneous shape evolution is achieved by tuning the degree of preferential adsorption of sodium dodecyl sulfate on the {111} faces of growing Cu2O crystals through pH variation. Scale bar: I mum.
引用
收藏
页码:1743 / +
页数:5
相关论文
共 24 条
  • [1] Morphological control of particles
    Adair, JH
    Suvaci, E
    [J]. CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2000, 5 (1-2) : 160 - 167
  • [2] Buckley H. E., 1951, CRYSTAL GROWTH
  • [3] Budevski E., 1996, ELECTROCHEMICAL PHAS
  • [4] Cu2O:: a catalyst for the photochemical decomposition of water?
    de Jongh, PE
    Vanmaekelbergh, D
    Kelly, JJ
    [J]. CHEMICAL COMMUNICATIONS, 1999, (12) : 1069 - 1070
  • [5] Cu2O:: Electrodeposition and characterization
    de Jongh, PE
    Vanmaekelbergh, D
    Kelly, JJ
    [J]. CHEMISTRY OF MATERIALS, 1999, 11 (12) : 3512 - 3517
  • [6] Cu2O as a photocatalyst for overall water splitting under visible light irradiation
    Hara, M
    Kondo, T
    Komoda, M
    Ikeda, S
    Shinohara, K
    Tanaka, A
    Kondo, JN
    Domen, K
    [J]. CHEMICAL COMMUNICATIONS, 1998, (03) : 357 - 358
  • [7] Surface-induced phase behavior of alkyltrimethylammonium bromide surfactants adsorbed to mica, silica, and graphite
    Liu, JF
    Ducker, WA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (40) : 8558 - 8567
  • [8] Shape control in epitaxial electrodeposition:: Cu2O nanocubes on InP(001)
    Liu, R
    Oba, F
    Bohannan, EW
    Ernst, F
    Switzer, JA
    [J]. CHEMISTRY OF MATERIALS, 2003, 15 (26) : 4882 - 4885
  • [9] Epitaxial electrodeposition of Cu2O films onto InP(001)
    Liu, R
    Bohannan, EW
    Switzer, JA
    Oba, F
    Ernst, F
    [J]. APPLIED PHYSICS LETTERS, 2003, 83 (10) : 1944 - 1946
  • [10] Single-crystal Cu2O formation on amorphous carbon electrode and effect of anions on the crystal habit of Cu2O particles
    Lu, DL
    Tanaka, K
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (07) : 2105 - 2109