The road to non-heme oxoferryls and beyond

被引：414

作者：

Que, Lawrence, Jr.

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[2] Univ Minnesota, Ctr Met Biocatalysis, Minneapolis, MN 55455 USA

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2007年 / 40卷 / 07期

关键词：

D O I：

10.1021/ar700024g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxoiron(IV) species are often implicated in the catalytic cycles of oxygen-activating non-heme iron enzymes. The paucity of suitable model complexes stimulated us to fill this void, and our synthetic efforts have afforded a number of oxoiron(IV) complexes. This Account provides a chronological perspective of the observations that contributed to the generation of the first non-heme iron(IV)oxo complexes in high yield and summarizes their salient properties to date.

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页码：493 / 500

页数：8

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