Crystalline small-molecule electrolytes

被引:43
作者
Zhang, Chuhong [1 ]
Andreev, Yuri G. [1 ]
Bruce, Peter G. [1 ]
机构
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
关键词
conducting materials; glymes; ionic conductors; materials science; solid electrolytes;
D O I
10.1002/anie.200604934
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Tunnel route: A new class of solid ionic conductors based on glymes and lithium salts is described. The structure of one example, (CH3O(CH2CH2O)4CH3) 05:- LiBF4, contains two types of tunnels filled by Li+ ions, which are lined by tetraglyme molecules or BF 4- ions, respectively (see picture; Li blue, B pink, C green, O red, F purple). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:2848 / 2850
页数:3
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