Surface-confined metalloporphyrin oligomers

被引：6

作者：

Van Ryswyk, H

Moore, EE

Joshi, NS

Zeni, RJ

Eberspacher, TA

Collman, JR

机构：

[1] Harvey Mudd Coll, Dept Chem, Claremont, CA 91711 USA

[2] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 43期

关键词：

electron transfer; metal-metal interactions; nanotechnology; porphyrinoids; surface chemistry;

D O I：

10.1002/anie.200460992

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The modular assembly of metalloporphyrin oligomers through the stepwise addition of Ru-porphyrin units and a bidentate linking ligand (L, see graphic) onto a surface-confined isonicotinate ligand is reported. Electrochemical measurements of the resulting oligomer show that electrons are transported along the length of its backbone.

引用

收藏

页码：5827 / 5830

页数：4

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