Halogen-induced selectivity in heterogeneous epoxidation is an electronic effect - fluorine, chlorine, bromine and iodine in the Ag-catalysed selective oxidation of ethene

被引：42

作者：

Lambert, RM ^{[1
]}

Cropley, RL ^{[1
]}

Husain, A ^{[1
]}

Tikhov, MS ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 10期

关键词：

D O I：

10.1039/b302620e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selectivity promotion in the Ag-catalysed heterogeneous epoxidation of ethene correlates with halogen electron affinity showing that it is an electronic phenomenon rather than a steric or geometrical effect.

引用

页码：1184 / 1185

页数：2

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