Direct methanol fuel cells: determination of fuel crossover in a polymer electrolyte membrane

被引:110
作者
Ramya, K [1 ]
Dhathathreyan, KS [1 ]
机构
[1] SPIC Sci Fdn, Energy Res Ctr, Madras 600032, Tamil Nadu, India
关键词
direct methanol fuel cells; permeability of methanol; electrochemical techniques; membrane porosity;
D O I
10.1016/S0022-0728(02)01476-6
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The crossover of methanol from anode to cathode is one of the important factors that affects the performance of direct methanol fuel cells that are being developed for portable power and transportation applications. We report an effective method for the determination of methanol permeability through simple electrochemical methods. The method has been applied to find the permeability factors for various methanol concentrations. An optimum concentration of methanol for operation of fuel cells using methanol as the fuel has also been determined based on the above results. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:109 / 115
页数:7
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