Reactivity of a new alkenyl phenyliodonium tosylate derived from methyl 3-aminocrotonate

被引：23

作者：

Papoutsis, I ^{[1
]}

Spyroudis, S ^{[1
]}

Varvoglis, A ^{[1
]}

机构：

[1] Univ Thessaloniki, Dept Chem, Organ Chem Lab, GR-54006 Salonika, Greece

来源：

TETRAHEDRON | 1998年 / 54卷 / 5-6期

关键词：

D O I：

10.1016/S0040-4020(97)10354-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methyl 3-aminocrotonate reacts with [hydroxy(tosyloxy)iodo]benzene to afford the corresponding E-2-phenyliodonio tosylate in good yield. This new alkenyl iodonium salt upon reaction with various nucleophiles offers an easy access to substituted enamine derivatives of crotonic acid. The reaction can be also extended to N-substituted crotonates. (C) 1997 Elsevier Science Ltd. All rights reserved.

引用

页码：1005 / 1012

页数：8

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