Ternary metal nitrides by the urea route

被引：34

作者：

Gomathi, A.

机构：

[1] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

[2] Jawaharlal Nehru Ctr Adv Sci Res, CSIR Ctr Excellence Chem, Bangalore 560064, Karnataka, India

来源：

MATERIALS RESEARCH BULLETIN | 2007年 / 42卷 / 05期

关键词：

nitrides; chemical synthesis;

D O I：

10.1016/j.materresbull.2006.08.021

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Interstitial molybdenum ternary nitrides, MnMo3N (M = Fe and Co, n = 3; M = Ni, n = 2), can be obtained by heating the molybdate precursors, FeMoO4, CoMoO4 and NiMoO4 with urea in the 1:12 molar ratio in the 900-1000 degrees C range. Fe3Mo3N and Co3Mo3N are obtained in pure form. The nickel nitride has the composition Ni2Mo3N and therefore is in admixture with nickel. All the nitrides have been characterized by various physical methods. (c) 2006 Elsevier Ltd. All rights reserved.

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页码：870 / 874

页数：5

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