Diphenyldichlorophosphonium trichloride-chlorine solvate 1:1, [PPh2Cl2]+Cl3-•Cl2:: An ionic form of diphenyltrichlorophosphorane.: Crystal structures of [PPh2Cl2]+Cl3-•Cl2 and [(PPh2Cl2)+]2[InCl5]2-

被引：37

作者：

Taraba, J ^{[1
]}

Zak, Z ^{[1
]}

机构：

[1] Masaryk Univ, Dept Inorgan Chem, Brno 61137, Czech Republic

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 11期

关键词：

D O I：

10.1021/ic034091n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An ionic form of diphenyltrichlorophosphorane, namely, diphenyldichlorophosphonium trichloride isolated as a dichlorine solvate (1), was obtained by treating PPh2Cl3 With excess chlorine. The identity of this species was established by single-crystal X-ray analysis and P-31, H-1, and Cl-35 NMR and Raman spectra. Bis(diphenyldichlorophosphonium) pentachloroindate (2) was obtained by the reaction of diphenyltrichlorophosphorane with indium trichloride in dichloromethane for comparison purposes. Its identity was determined by P-31 NMR spectra and single-crystal X-ray analysis.

引用

页码：3591 / 3594

页数：4

共 22 条

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