Compatibility of lithium ion conductive sulfide glass with carbon-lithium electrode

被引：38

作者：

Takada, K

Nakano, S

Inada, T

Kajiyama, A

Sasaki, H

Kondo, S

Watanabe, M

机构：

[1] Natl. Inst. for Materials Science, Advanced Materials Laboratory

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2003年 / 150卷 / 03期

关键词：

D O I：

10.1149/1.1545453

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Electrochemical properties of graphite were investigated using SiS2-based glass or P2S5-based glass as a solid electrolyte. Graphite showed reversible electrode reactions in the P2S5-based glass, while it did not in the SiS2-based one. The results of X-ray diffractometry and Raman spectroscopy indicated that the SiS2-based glass was reduced as side reactions instead of the intercalation of lithium ions into graphite during the reduction, resulting in the poor reversibility. (C) 2003 The Electrochemical Society.

引用

收藏

页码：A274 / A277

页数：4

相关论文

共 33 条

[1]

[Anonymous], APPL PHYS LETT

[2] IONIC-CONDUCTIVITY OF SOLID ELECTROLYTES BASED ON LITHIUM TITANIUM PHOSPHATE [J].

AONO, H ;

SUGIMOTO, E ;

SADAOKA, Y ;

IMANAKA, N ;

ADACHI, G .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (04) :1023-1027

[3] SYNTHESIS AND ELECTROCHEMICAL PROPERTIES OF LITHIUM ION CONDUCTIVE GLASS, LI3PO4-LI2S-SIS2 [J].

AOTANI, N ;

IWAMOTO, K ;

TAKADA, K ;

KONDO, S .

SOLID STATE IONICS, 1994, 68 (1-2) :35-39

[4] Experimental Raman scattering investigation of phonon anharmonicity effects in Li2S [J].

Bertheville, B ;

Bill, H ;

Hagemann, H .

JOURNAL OF PHYSICS-CONDENSED MATTER, 1998, 10 (09) :2155-2169

[5] ELECTROCHEMICAL SYNTHESIS OF BINARY GRAPHITE-LITHIUM INTERCALATION COMPOUNDS [J].

BILLAUD, D ;

HENRY, FX ;

WILLMANN, P .

MATERIALS RESEARCH BULLETIN, 1993, 28 (05) :477-483

[6] THE NASICON-TYPE TITANIUM PHOSPHATES LITI2(PO4)3, NATI2(PO4)3 AS ELECTRODE MATERIALS [J].

DELMAS, C ;

NADIRI, A ;

SOUBEYROUX, JL .

SOLID STATE IONICS, 1988, 28 :419-423

[7] INTERCALATION OF LITHIUM INTO GRAPHITE AND OTHER CARBONS [J].

GUERARD, D ;

HEROLD, A .

CARBON, 1975, 13 (04) :337-345

[8] Electrochemical properties for the lithium ion conductive (100-x)(0.6Li2S•0.4SiS2)•xLi4SiO4 oxysulfide glasses [J].

Hayashi, A ;

Tatsumisago, M ;

Minami, T .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (09) :3472-3475

[9] Characterization of Li2S-SiS2-LixMOy (M=Si, P, Ge) amorphous solid electrolytes prepared by melt-quenching and mechanical milling [J].

Hayashi, A ;

Yamashita, H ;

Tatsumisago, M ;

Minami, T .

SOLID STATE IONICS, 2002, 148 (3-4) :381-389

[10] THERMAL AND ELECTRICAL-PROPERTIES OF RAPIDLY QUENCHED GLASSES IN THE SYSTEMS LI2S-SIS2-LI(X)MO(Y)(LI(X)MO(Y)=LI4SIO4,LI2SO4) [J].

HIRAI, K ;

TATSUMISAGO, M ;

MINAMI, T .

SOLID STATE IONICS, 1995, 78 (3-4) :269-273

← 1 2 3 4 →