Poly(α-τ-butoxy-ω-styrylo-glycidol):: a new reactive surfactant

被引：67

作者：

Dworak, A

Panchev, I

Trzebicka, B

Walach, W

机构：

[1] Polish Acad Sci, Inst Coal Chem, PL-44102 Gliwice, Poland

[2] Bulgarian Acad Sci, Inst Polymers, Sofia, Bulgaria

来源：

POLYMER BULLETIN | 1998年 / 40卷 / 4-5期

关键词：

D O I：

10.1007/s002890050277

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(alpha-t-butoxy-omega-styrylo-ethoxy ethyl glycidyl ether) was synthesized via the termination of the potassium t-butoxide initiated anionic polymerization of ethoxy ethyl glycidyl ether with p-chloromethylstyrene. The macromonomer was copolymerized with styrene. Subsequent hydrolysis of the copolymers leads to polystyrene - graft - polyglycidol. Poly(alpha-t-butoxy-omega-styrylo-glycidol), synthesized through the hydrolysis of the macromonomer so obtained, acts as reactive emulsifier (surfmer) in the emulsion copolymerization of styrene in water.

引用

页码：461 / 468

页数：8

共 16 条

[1] GRAFT-COPOLYMERS HAVING HYDROPHOBIC BACKBONE AND HYDROPHILIC BRANCHES .5. MICROSPHERES OBTAINED BY THE COPOLYMERIZATION OF POLY(ETHYLENE GLYCOL) MACROMONOMER WITH METHYL-METHACRYLATE [J].