Determination of linuron in water samples by high performance liquid chromatography after preconcentration with octadecyl silanized magnetite

A sensitive and selective batch adsorption method is proposed for the preconcentration and determination of linuron. Linuron was preconcentrated on octadecyl silanized (ODS) magnetite as an adsorbent and then determined by high performance liquid chromatography (HPLC). Several parameters on the recovery of the analyte were investigated. The experimental results showed that it was possible to obtain sufficient preconcentration efficiency when the solution pH was 6 using 100 mL of sample solution containing 1.0 mu g of linuron and 3 mL of ethanol as a desorption solution. Recovery of linuron was 50.7 +/- 1.9% with a relative standard deviation for five determinations of 3.0% under optimum conditions. The calibration curve of linuron was linear up to 200 ng mL(-1) with a correlation coefficient of 0.998 and the detection limit (3S/N) was 1.0 ng mL(-1). The capacity of the adsorbent was also examined and found to be 0.15 mg g(-1) for linuron. ODS-magnetite is suitable for repeated use without decreasing recovery at least 4 adsorption-desorption cycles. The proposed method was successfully applied to the determination of linuron in river water with high precision and accuracy. (c) 2006 Elsevier B.V. All rights reserved.