Electroanalytical application of modified diamond electrodes

被引:65
作者
Ivandini, TA
Sato, R
Makide, Y
Fujishima, A
Einaga, Y
机构
[1] Keio Univ, Fac Sci & Technol, Dept Chem, Yokohama, Kanagawa 2238522, Japan
[2] Univ Tokyo, Radioisotope Ctr, Bunkyo Ku, Tokyo 1130032, Japan
[3] Kanagawa Acad Sci & Technol, KSP, Kawasaki, Kanagawa 2130012, Japan
关键词
chemical electrodes; sensors; diamond electrodes; ion implantation; electrochemical analysis; metal-modified electrodes;
D O I
10.1016/j.diamond.2004.07.004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Metal-modified diamond electrodes were fabricated by using ion implantation method for electroanalytical applications. Nickel and copper ion were implanted at a different film of boron-doped diamond (BDD) with a dose of 5 x 10(14) cm(-2) for each type of ion. The electrochemical behavior has been studied for glucose oxidation in alkaline media by using cyclic voltarnmetty and flow injection analysis. Those electrodes exhibited high catalytic activity and excellent electrochemical stability with low background current even after strong ultrasonication in the cleaning process. The results indicate that metal-implanted method could be a promising method for controlling the electrochemical properties of diamond electrodes. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:2003 / 2008
页数:6
相关论文
共 22 条
[1]  
Buchberger W, 1996, FRESEN J ANAL CHEM, V354, P797
[2]   STUDY OF A NICKEL-CATALYZED GLASSY-CARBON ELECTRODE FOR DETECTION OF CARBOHYDRATES IN LIQUID-CHROMATOGRAPHY AND FLOW-INJECTION ANALYSIS [J].
CASELLA, IG ;
DEIMONI, F ;
CATALDI, TRI .
ANALYTICA CHIMICA ACTA, 1991, 248 (01) :117-125
[3]   OXIDATION OF ORGANIC COMPOUNDS AT A NICKEL ANODE IN ALKALINE SOLUTION [J].
FLEISCHMANN, M ;
KORINEK, K ;
PLETCHER, D .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1971, 31 (01) :39-+
[4]   Gradient liquid chromatography of leucine-enkephalin peptide and its metabolites with electrochemical detection using highly boron-doped diamond electrode [J].
Ivandini, TA ;
Sarada, BV ;
Terashima, C ;
Rao, TN ;
Tryk, DA ;
Ishiguro, H ;
Kubota, Y ;
Fujishima, A .
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2003, 791 (1-2) :63-72
[5]   Electrochemical oxidation of underivatized-nucleic acids at highly boron-doped diamond electrodes [J].
Ivandini, TA ;
Sarada, BV ;
Rao, TN ;
Fujishima, A .
ANALYST, 2003, 128 (07) :924-929
[6]   Ion-implantation in diamond and diamond films: Doping, damage effects and their applications [J].
Kalish, R .
APPLIED SURFACE SCIENCE, 1997, 117 :558-569
[7]   Fabrication of metal oxide-diamond composite films by electrophoretic deposition and anodic dissolution [J].
Kamada, K ;
Maehara, K ;
Mukai, M ;
Ida, S ;
Matsumoto, Y .
JOURNAL OF MATERIALS RESEARCH, 2003, 18 (12) :2826-2831
[8]  
LUO PF, 1996, ANAL CHEM, V354, P767
[9]   Hydrogen and oxygen evolution on boron-doped diamond electrodes [J].
Martin, HB ;
Argoitia, A ;
Landau, U ;
Anderson, AB ;
Angus, JC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (06) :L133-L136
[10]   Platinum particles deposited on synthetic boron-doped diamond surfaces.: Application to methanol oxidation [J].
Montilla, F ;
Morallón, E ;
Duo, I ;
Comninellis, C ;
Vázquez, JL .
ELECTROCHIMICA ACTA, 2003, 48 (25-26) :3891-3897