Gold-Catalyzed Cross-Couplings: New Opportunities for C-C Bond Formation

被引：227

作者：

Garcia, Pierre ^{[2
]}

Malacria, Max ^{[2
]}

Aubert, Corinne ^{[2
]}

Gandon, Vincent ^{[1
]}

Fensterbank, Louis ^{[2
]}

机构：

[1] Univ Paris Sud, CNRS, UMR 8182, F-91405 Orsay, France

[2] Univ Paris 06, CNRS, UMR 7201, UPMC, F-75005 Paris, France

来源：

CHEMCATCHEM | 2010年 / 2卷 / 05期

关键词：

chemoselectivity; cross-coupling; gold; homogeneous catalysis; supported catalysts; HETEROGENEOUS CATALYSTS; PALLADIUM COMPLEXES; PROPARGYLIC ESTERS; PHENYLBORONIC ACID; ATOM ECONOMY; NANOPARTICLES; GOLD(III); HYDROGENATION; PLATINUM; AU(III);

D O I：

10.1002/cctc.200900319

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cross-coupling is a powerful tool for the rapid construction of highly valuable compounds. In this area of chemical transformations, new catalysts have recently emerged. Combining both a pi-Lewis acid character and interesting redox properties, gold has proven to be an expedient choice for mediating such transformations. Recent developments in the use of gold to mediate a variety of C-C coupling reactions are summarized, including Suzuki and Sonogashira cross-coupling reactions, as well as the development of tandem processes and the combination of gold with palladium to enable C-C bond formation via transmetalation.

引用

页码：493 / 497

页数：5

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