An original heterodinuclear VO2+,Gd3+ complex with a nonet ground state

被引：72

作者：

Costes, JP ^{[1
]}

Dupuis, A ^{[1
]}

Laurent, JP ^{[1
]}

机构：

[1] Univ Toulouse 3, CNRS UPR 8241, Chim Coordinat Lab, F-31077 Toulouse, France

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 05期

关键词：

D O I：

10.1039/a800346g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the vanadyl complex of N,N'-bis(3-methoxysalicylidene)-1 ,2-diamino-2-methylpropane (H2L) with Gd(NO3)(3) . 5H(2)O yielded a dinuclear complex (LVOGdIII)-O-IV(NO3)(3) .(CH3)(2)CO which presents a ferromagnetic interaction between the paramagnetic (S = 1/2) vanadyl and the gadolinium (S = 7/2) ions, with a J value of 1.3 cm(-1).

引用

页码：735 / 736

页数：2

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