Synthesis of (2S,3R,4S)-3,4-methanoproline and analogues by cyclopropylidene insertion

被引：41

作者：

Tverezovsky, VV

Baird, MS

Bolesov, IG

机构：

[1] UNIV WALES, DEPT CHEM, BANGOR, GWYNEDD, WALES

[2] MOSCOW MV LOMONOSOV STATE UNIV, DEPT CHEM, MOSCOW, RUSSIA

来源：

TETRAHEDRON | 1997年 / 53卷 / 43期

关键词：

D O I：

10.1016/S0040-4020(97)00988-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Intramolecular insertion of single enantiomers of cyclopropylidenes into 5,6-related C-H bonds adjacent to nitrogen has been used to obtain enantiomerically pure methanoproline and a number of analogues with a high degree of one- or two-fold asymmetric induction. (C) 1997 Elsevier Science Ltd.

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页码：14773 / 14792

页数：20

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