Aqueous hydrogenation of carbon dioxide catalysed by water-soluble ruthenium aqua complexes under acidic conditions

被引：129

作者：

Hayashi, H

Ogo, S

Fukuzumi, S

机构：

[1] Osaka Univ, Dept Mat & Life Sci, Grad Sch Engn, Suita, Osaka 5650871, Japan

[2] Japan Sci & Technol Agcy JST, PRESTO, Suita, Osaka 5650871, Japan

[3] Japan Sci & Technol Agcy JST, CREST, Suita, Osaka 5650871, Japan

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 23期

关键词：

D O I：

10.1039/b411633j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogenation of carbon dioxide (P(H-2/CO2) = 5.5/2.5 MPa) into formic acid (HCOOH) under acidic conditions ( pH 2.5-5.0) in water has been achieved by using water-soluble ruthenium aqua catalysts [(eta(6)-C6Me6) Ru-II(L)(OH2)] SO4 ( L = 2,2'-bipyridine or 4,4'-dimethoxy-2, 2'- bipyridine).

引用

收藏

页码：2714 / 2715

页数：2

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