Chiral conducting polymers

被引：218

作者：

Kane-Maguire, Leon A. P. ^{[1
]}

Wallace, Gordon G. ^{[1
]}

机构：

[1] Univ Wollongong, AIIM Facil, Intelligent Polymer Res Inst, ARC Ctr Excellence Electromat Sci, Wollongong, NSW 2522, Australia

来源：

CHEMICAL SOCIETY REVIEWS | 2010年 / 39卷 / 07期

关键词：

OPTICALLY-ACTIVE POLYANILINE; POLYTHIOPHENE DERIVATIVES BEARING; CHIROPTICAL PROPERTIES; LIQUID-CRYSTAL; AMINO-ACID; ELECTROCHEMICAL POLYMERIZATION; ACHIRAL MONOMERS; ENANTIOSELECTIVE ELECTRODES; SUPRAMOLECULAR CHIRALITY; CAMPHORSULFONIC ACID;

D O I：

10.1039/b908001p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This critical review describes the preparation and properties of a relatively new class of chiral macromolecules, namely chiral conducting polymers. It focuses in particular on examples based on polypyrrole, polythiophene and polyaniline. They possess remarkable properties, combining not only chirality with electrical conductivity but also the ability to undergo facile redox and pH switching. These unique properties have opened up a range of exciting new potential applications, including as chiral sensors, as novel stationary phases for chiral separations, and as chiral electrodes for electrochemical asymmetric synthesis (153 references).

引用

页码：2545 / 2576

页数：32

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