Short-ranged attractive colloids: What is the gel state ?

被引:16
作者
Zaccarelli, E [1 ]
Sciortino, F [1 ]
Buldyrev, SV [1 ]
Tartaglia, P [1 ]
机构
[1] Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
来源
UNIFYING CONCEPTS IN GRANULAR MEDIA AND GLASSES | 2004年
关键词
D O I
10.1016/B978-044451607-7/50015-7
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
We evaluate thermodynamic, geometric and dynamic properties of a short-ranged square well binary mixture to provide a coherent picture of this simple, but rich, model for colloidal interactions. In particular, we compare the location, in the temperature-packing fraction plane, of the geometrical percolation locus, the metastable liquid-gas spinodal and the glass transition lines. Such comparison provides evidence that the gel-state can not be related to the attractive glass transition line directly. Indications are given for the possibility of an indirect link between the two, via an arrested phase separation process. We finally discuss the possibility that a spherical short range attraction may not be sufficient to produce an equilibrium cluster phase at low packing fraction and low temperatures.
引用
收藏
页码:181 / 194
页数:14
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