Densities and viscosities for binary mixtures of butylamine with aliphatic alcohols

被引:45
作者
Weng, WL [1 ]
机构
[1] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 304, Taiwan
关键词
D O I
10.1021/je990328b
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities and viscosities were measured for the binary mixtures of butylamine with 1-butanol, 1-pentanol, 1-hexanol, 1-heptanol, and 1-octanol at 303.15 K, 313.15 K, and 323.15 K over the entire composition range. Excess molar volumes and viscosity deviations were calculated at various temperatures. Both excess molar volumes and viscosity deviations are negative for all investigated systems. A Redlich-Kister type equation was applied to fit the isothermal excess volumes and viscosity deviations, and McAllister's three-body and four-body interaction models were also used to correlate the kinematic viscosities.
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页码:606 / 609
页数:4
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