Oxygen adsorption on Au clusters and a rough Au(111) surface: The role of surface flatness, electron confinement, excess electrons, and band gap

It has been shown recently that while bulk gold is chemically inert, small Au clusters are catalytically active. The reasons for this activity and its dramatic dependence on cluster size are not understood. We use density functional theory to study O-2 binding to Au clusters and to a Au(111) surface modified by adsorption of Au clusters on it. We find that O-2 does not bind to a flat face of a planar Au cluster, even though it binds well to its edge. Moreover, O-2 binds to Au clusters deposited on a Au(111) surface, even though it does not bind to Au(111). This indicates that a band gap is not an essential factor in binding O-2, but surface roughness is. Adding electrons to the surface of a Au(111) slab, on which one has deposited a Au cluster, increases the binding energy of O-2. However, adding electrons to a flat Au surface has no effect on O-2 binding energy. These observations have a simple explanation: in clusters and in the rough surface, the highest occupied molecular orbital (HOMO) is localized and its charge density sticks out in the vacuum. This facilitates charge transfer into the pi* orbital of O-2, which induces the molecule to bind to gold. A flat face of a cluster or a flat bulk surface tends to delocalize the HOMO, diminishing the ability of the surface to bind O-2. The same statements are true for the LUMO orbital, which is occupied by the additional electron given to the system to charge the system negatively. (C) 2003 American Institute of Physics.