Converting methane by using an RF plasma reactor

被引:74
作者
Hsieh, LT
Lee, WJ [1 ]
Chen, CY
Chang, MB
Chang, HC
机构
[1] Natl Cheng Kung Univ, Dept Environm Engn, Tainan 70101, Taiwan
[2] Natl Cheng Kung Univ, Dept Chem Engn, Tainan 70101, Taiwan
[3] Natl Cent Univ, Grad Inst Environm Engn, Chungli 32054, Taiwan
关键词
plasma; CH4; RF; FTIR; decomposition; sensitivity;
D O I
10.1023/A:1021650516043
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A radio-frequency (RF) plasma system was used to convert methane gas. The reactants and final products were analyzed by using an FTIR (Fourier transform infrared spectrometer). The effects of plasma operational parameters, including feeding concentration (C) of CH4, operational pressure (P) in the RF plasma reactor, total gas flow rate (Q) and input power wattage (W) for CH4 decomposition were evaluated The results showed that the CH4 decomposition fraction increases with increasing power input, decreasing operational pressure in the RF plasma reactor, decreasing CH4 feeding concentration, and decreasing total gas flow rate. In addition, mathematical models based on the obtained experimental data were developed and tested by means of sensitivity analysis.
引用
收藏
页码:215 / 239
页数:25
相关论文
共 36 条
[1]  
ABDELAAL MK, 1990, THESIS ILLINOIS I TE
[2]  
[Anonymous], [No title captured]
[3]   ACETONE CONVERSION IN A LOW-PRESSURE OXYGEN-SURFACE WAVE PLASMA [J].
ARNO, J ;
BEVAN, JW ;
MOISAN, M .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1995, 29 (08) :1961-1965
[4]   Detoxification of trichloroethylene in a low-pressure surface wave plasma reactor [J].
Arno, J ;
Bevan, JW ;
Moisan, M .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1996, 30 (08) :2427-2431
[5]  
Back M.H., 1983, PYROLYSIS THEORY IND
[6]   BOND ENERGIES [J].
BENSON, SW .
JOURNAL OF CHEMICAL EDUCATION, 1965, 42 (09) :502-&
[7]   DECOMPOSITION OF DILUTE CONCENTRATIONS OF CARBON-TETRACHLORIDE IN AIR BY AN ELECTRON-BEAM GENERATED PLASMA [J].
BROMBERG, L ;
COHN, DR ;
KOCH, M ;
PATRICK, RM ;
THOMAS, P .
PHYSICS LETTERS A, 1993, 173 (03) :293-299
[8]   OXIDATIVE PYROLYSIS OF METHANE TO HIGHER HYDROCARBONS - EFFECTS OF WATER IN FEED [J].
CHOUDHARY, VR ;
CHAUDHARI, ST ;
RAJPUT, AM .
AICHE JOURNAL, 1991, 37 (06) :915-922
[9]   Oxidative conversion of methane to syngas over LaNiO3 perovskite with or without simultaneous steam and CO2 reforming reactions: Influence of partial substitution of La and Ni [J].
Choudhary, VR ;
Uphade, BS ;
Belhekar, AA .
JOURNAL OF CATALYSIS, 1996, 163 (02) :312-318
[10]  
CLELAND TA, 1987, PLASMA CHEM PLASMA P, V7, P370