Fabrication and electrochemical behavior of multilayer films containing 1:12 phosphomolybdic anions and their electrocatalytic oxidation of ascorbic acid

被引：51

作者：

Sun, CQ ^{[1
]}

Zhang, JD ^{[1
]}

机构：

[1] Jilin Univ, Dept Chem, Changchun 130023, Peoples R China

来源：

ELECTROCHIMICA ACTA | 1998年 / 43卷 / 08期

关键词：

chemically modified electrode; electrocatalysis; ascorbic acid; 1 : 12 phosphomolybdic anion; multilayer films;

D O I：

10.1016/S0013-4686(97)00215-6

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A novel kind of multilayer film containing 1:12 phosphomolybdic anions was achieved on the surface of gold electrode by alternate deposition of 1:12 phosphomolybdic anions with water-soluble bipolar pyridine salt (PyC6BPC6Py). The electrochemical behavior of the multilayer films was described. The catalytic effect of the multilayer films on the oxidation of ascorbic acid was studied. (C) 1997 Elsevier Science Ltd. All rights reserved.

引用

页码：943 / 950

页数：8

共 23 条

[1] MODIFICATION OF POLYANILINE FILMS WITH HETEROPOLYANIONS - ELECTROCATALYTIC REDUCTION OF OXYGEN AND PROTONS [J].

BIDAN, G ;

GENIES, EM ;

LAPKOWSKI, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (08) :533-535

[2] ONE-STEP ELECTROCHEMICAL IMMOBILIZATION OF KEGGIN-TYPE HETEROPOLYANIONS IN POLY(3-METHYLTHIOPHENE) FILM AT AN ELECTRODE SURFACE - ELECTROCHEMICAL AND ELECTROCATALYTIC PROPERTIES [J].

BIDAN, G ;

GENIES, EM ;

LAPKOWSKI, M .

SYNTHETIC METALS, 1989, 31 (03) :327-334

[3] POLYPYRROLE AND POLY(N-METHYLPYRROLE) FILMS DOPED WITH KEGGIN-TYPE HETEROPOLYANIONS - PREPARATION AND PROPERTIES [J].

BIDAN, G ;

GENIES, EM ;

LAPKOWSKI, M .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 251 (02) :297-306

[4] BUILDUP OF ULTRATHIN MULTILAYER FILMS BY A SELF-ASSEMBLY PROCESS .1. CONSECUTIVE ADSORPTION OF ANIONIC AND CATIONIC BIPOLAR AMPHIPHILES ON CHARGED SURFACES [J].

DECHER, G ;

HONG, JD .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1991, 46 :321-327

[5] PROOF OF MULTILAYER STRUCTURAL ORGANIZATION IN SELF-ASSEMBLED POLYCATION POLYANION MOLECULAR FILMS [J].

DECHER, G ;

LVOV, Y ;

SCHMITT, J .

THIN SOLID FILMS, 1994, 244 (1-2) :772-777

[6]

DING S, 1993, J ELECTROANAL CHEM, V87, P354

[7]

DONG S, 1987, J CHEM SOC CHEM COMM, P187

[8] ELECTROCHEMICAL STUDY OF ISOPOLYOXOMETALLATES AND HETEROPOLYOXOMETALLATES FILM MODIFIED MICROELECTRODES .1. PRETREATMENT AND MODIFICATION OF THE MO80-26(4-) MODIFIED CARBON-FIBER MICROELECTRODE [J].

DONG, SJ ;

WANG, BX .

ELECTROCHIMICA ACTA, 1992, 37 (01) :11-16

[9] SURFACE MODIFICATIONS WITH HETEROPOLY AND ISOPOLY OXOMETALATES .1. QUALITATIVE ASPECTS OF THE ACTIVATION OF ELECTRODE SURFACES TOWARDS THE HYDROGEN EVOLUTION REACTION [J].

KEITA, B ;

NADJO, L .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 243 (01) :87-103

[10] SURFACE MODIFICATIONS WITH HETEROPOLY AND ISOPOLY OXOMETALATES .2. ELECTROCATALYTIC BEHAVIOR OF GLASSY-CARBON SURFACES MODIFIED WITH 17-TUNGSTO, 1-MOLYBDO-DIPHOSPHATE [J].

KEITA, B ;

NADJO, L ;

SAVEANT, JM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 243 (01) :105-116

← 1 2 3 →