Saccharin: a combined experimental and computational thermochemical investigation of a sweetener and sulfonamide

被引：26

作者：

Matos, MAR

Miranda, MS

Morais, VMF

Liebman, JF ^{[1
]}

机构：

[1] Univ Maryland Baltimore Cty, Dept Chem & Biochem, Baltimore, MD 21250 USA

[2] Univ Porto, Fac Ciencias, Dept Quim, Ctr Invest Quim, P-4169007 Oporto, Portugal

[3] Univ Porto, ICBAS, Inst Ciencias Biomed Abel Salazar, P-4099003 Oporto, Portugal

来源：

MOLECULAR PHYSICS | 2005年 / 103卷 / 2-3期

关键词：

D O I：

10.1080/00268970512331316175

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The standard molar enthalpies of combustion, sublimation, and formation in the crystalline and gaseous phase at a temperature of 298.15 K have been experimentally determined for saccharin and for benzenesulfonamide. These compounds were also studied theoretically using density functional theory, the B3LYP functional and extended basis sets.

引用

页码：221 / 228

页数：8

共 42 条

[1] THERMOCHEMISTRY OF ARENE CHROMIUM TRICARBONYLS AND STRENGTHS OF ARENE-CHROMIUM BONDS [J].